Shcherbakov I.N., Gasanov B.G. Research on the Adhesion of Antifriction Composite Double-Layer Corrosion-Resistant Nickel-Phosphorous Coatings Modified with MoS2

DOI: 10.18503/1995-2732-2022-20-2-73-81

Abstract

Relevance. The paper provides the rationale for creating double-layer composite antifriction modified nickel-phosphorus coatings produced by a chemical deposition on the samples from structural, heat-treatable steels. Methods Applied. Molybdenum disulfide was chosen as a modifier, which can be introduced into the coating matrix of both the first and second layers. The paper describes technological features of the deposition of MoS2-modified nickel-phosphorus coatings on products made of P40 and P40Kh powder steels, and proposes schemes for a possible distribution of the modifier in the coating. To test the adhesion of nickel-phosphorus coatings, the authors used the methods applied for anti-friction coatings on products made of steels and alloys with a thickness of 3 mm or less. Originality. The paper shows the kinetic features of shaping the structure of nickel-phosphorus coatings modified with molybdenum disulfide and efficiency of applying a second layer based on aluminum and chromium phosphate onto them by chemical deposition. It has been established that the modifier should be introduced into the solution for chemical deposition 2–3 minutes after the start of nickel plating in order to increase adhesion to the base. Results. The experimental studies are presented to evaluate the adhesion of nickel-phosphorus coatings modified with MoS2. The paper shows efficiency of the proposed method of applying double-layer composite coatings on products made of heat-treatable sintered and hot-stamped powder steels. Practical Relevance. Based on the experimental studies, the authors proposed technological options to produce composite coatings with different positions of the modifier, improving the functional properties of structural powder steels, widely used in mechanical engineering for manufacturing parts of various configurations.

Keywords

composite coating, powder steel, adhesion, modifier, binder, nickel-phosphorus, molybdenum disulfide, corrosion resistance, friction coefficient.

For citation

Shcherbakov I.N., Gasanov B.G. Research on the Adhesion of Antifriction Composite Double-Layer Corrosion-Resistant Nickel-Phosphorous Coatings Modified with MoS2.Vestnik Magnitogorskogo Gosudarstvennogo Tekhnicheskogo Universiteta im. G.I. Nosova [Vestnik of Nosov Magnitogorsk State Technical University]. 2022, vol. 20, no. 2, pp. 73–81. https://doi.org/10.18503/1995-2732-2022-20-2-73-81

Shcherbakov I.N. Don State Technical University, Rostov-on-Don, Russia

Gasanov B.G. South-Russian State Polytechnic University (NPI), Novocherkassk, Russia

1. KhopinP.N., ShishkinS.V. Tribologiya: uchebnikdlyavuzov[Tribology: textbook for universities]. Moscow: Yurayt Publishing House, 2021, 236 p. (In Russ.)

2. Frolov K.V. Metody sovershenstvovaniya mashin i sovremennye problemy mashinovedeniya [Methods for improving machines and modern problems of mechanical engineering]. Moscow: Mechanical Engineering, 1984, 224 p. (In Russ.)

3. Vishnyakov L.R., Grudina T.V., Kadyrov V.Kh. et al. Ed. by Karpinos D.M. Kompozitsionnye materialy: spravochnik [Composite materials: reference book]. Kyiv: Naukova dumka, 1985, 592 p. (In Russ.)

4. Ivanov D.A., Sitnikov A.I., Shlyapin S.D. Ed. by Ilina A.A. Kompozitsionnye materialy: ucheb. posobie dlya vuzov [Composite materials: study guide for universities]. Moscow: Yurayt Publishing House, 2021, 253 p. (In Russ.)

5. Grinberg P.B., Korotaev D.N., Orlov P.V., Vershinin G.A., Tarasov E.E., Ivanova E.V. Producing nanostructured topocomposite coatings by cascade cross effect. Dinamika sistem, mekhanizmov i mashin [Dynamics of Systems, Mechanisms and Machines], 2018, vol. 6, no. 2, pp. 171–177. (In Russ.)

6. Gasanov B.G., Tamadaev V.G., Bogachev V.O., Makhmudova E.R. Kinetics of the dielectric coating formation on iron powders to produce soft magnetic composite materials. Izvestiya vuzov. Poroshkovaya metallurgiya i funktsionalnye pokrytiya [Proceedings of Universities. Powder Metallurgy and Functional Coatings], 2019, no. 4, pp. 44–54. DOI: dx.doi.org/10.17073/1997-308X-2019-4-44-54

7. Shcherbakov I.N. Basic concept of tribocrystalochemistry of composition antifriction coatings. ICMTMTE 2020. IOP Conf. Series: Materials Science and Engineering, 971 (2020), 032021, IOP Publishing. DOI:10.1088/1757-899X/971/3/032021)

8. Ivanov V.V., Popov S.I., Selemeneva E.M., Babazhanov N.T. Study of technological characteristics of the process of formation of vibration mechanochemical oxide coating. The 15th International Scientific and Technical Conference “Dynamics of Technical Systems” (DTS-2019): AIP Conference Proceedings, vol. 2188, pp. 020015, 2019. doi.org/10.1063/1.5138389 (Rostov-on-Don, Russia, 11–13 September 2019).

9. Korotaev D.N., Tarasov E.E., Poleschenko K.N., Eremin E.N., Ivanova E.V. Formation of wear resistant nanostructural topocomposite coatings on metal materials by ionic-plasma processing. Journal of Physics: Conference Series, 2018, vol. 1050(1), 012037. DOI: 10.1088/1742-6596/1050/1/012037

10. Shulga G.I., Kolesnichenko A.O., Sirotin P.V., Lebedinsky I.Yu., Skrynnikov E.V., Vasilyev M.A. Optimization of technology for production of products of deep drawing sheet steels with the use of lubricants in universal software system ANSYS Workbench. Published online on 07 November 2018. DOI: https://doi.org/10.1051/matecconf/201822601028.

11. Shcherbakov I.N. Basic concept of tribocrystalochemistry of composition antifriction coatings. ICMTMTE 2020. IOP Conf. Series: Materials Science and Engineering, 971 (2020), 032021, IOP Publishing. DOI:10.1088/1757-899X/971/3/032021

12. Shcherbakov I.N. Composite antifriction coating modified with copper complex and fluoropolymer. Dynamics of Technical Systems (DTS 2020), IOP Conf. Series: Materials Science and Engineering, 1029 (2021), 012028, IOP Publishing. DOI:10.1088/1757-899X/1029/1/012028

13. Kostetsky B.I., Natanson M.E., Bershadsky L.I. Mekhanokhimicheskie protsessy pri granichnom trenii [Mechanochemical processes with boundary friction]. Moscow: Science, 1972, 170 p. (In Russ.)

14. Sayfulin R.S. Kompozitsionnye pokrytiya i materialy [Composite coatings and materials]. Moscow: Chemistry, 1977, 272 p. (In Russ.)

15. Trofimov G.E., Shcherbakov I.N., Shevchenko M.Yu., Loginov V.T., Derlugyan P.D., Derlugyan F.P. Sposob polucheniya kompozitsionnogo antifriktsionnogo pokrytiya na izdelii iz stali [A method of producing a composite anti-friction coating on a steel product]. Patent RU, no. 24555391, 2012.

16. Sinelnikova V.S.,Podergin V.A., Rechkin V.N.Alyuminidy [Aluminides]. Kyiv: Naukova dumka, 1965. 242 p. (In Russ.)

17. Glinka N.L. Obshchaya khimiya [General chemistry]. Moscow: KnoRus, 2019, 360 p. (In Russ.)